Copper sealing rings sit between the head and the exhaust manifolds on 72-78 engines. 79 engines have a square port design that seal differently. ALWAYS use new rings: they are inexpensive and you only need 4 per engine.
In the photo above, the left ring is new and is usually 2.0-2.2mm thick. If you were to mount the manifold without the rings you would find that the the manifolds just barely seal against the exhaust port. Therefore, the thickness of the ring, provides 2mm of crush when installed.
The middle ring shows what happens when the exhaust doesn't seal properly. The dark side on the left is where the exhaust leaked out and the right side is where the ring made a good seal with the engine. This was not the fault of the ring but the fault of the manifold sealing surface. Remember you are often trying to mate a rebuilt head with an original heaterbox. Who knows what VW did at the factory to match parts so you have to make sure the fit is correct especially when the parts come from more than one engine and have some degree of wear.
The ring on the right has been annealed with a propane or MAPP torch. The idea is to soften the copper so it can crush between the head and the exhaust manifold. There is a visual clue that it's been annealed: you can often see the oxidization from the heating process and a slight color change. The real test is to drop it 6" onto the concrete. If it makes a ringing sound, then it has not been annealed. You should also be able to bend it (be careful) when it's annealed.
At first I was skeptical of this method believing that the heat of the exhaust parts would anneal the copper and when you re-torqued the exhaust you would achieve some more crush on the copper ring but that's not the case. If you drop an old exhaust sealing ring on the floor it will make a metallic sound. This tells you that the heat of the exhaust is not hot enough to soften the copper. The torch is the only way to work the copper so it's soft. It also may enlarge the ring slightly for a tighter fit.
Anneal the ring on a torch proof surface such as a fire brick. You can work directly on a concrete surface but be warned that concrete contains moisture that might turn to gas and explode under heating. Wear a face mask so you aren't breathing in vapors from the copper or the torch and have some eye protection. Use an infrared gun to measure the surface temperature of the rings by moving the flame away for a moment and once you hit 900F pick up the ring with pliers and drop the ring in a can of water to quench it. NEVER touch the ring until it's been cooled by the water (instantly). Drop it on the floor again and notice it doesn't make a metallic sound.
VW did not anneal the rings but this is a good technique to help seal a used head to a used heat exchanger. I wouldn't bet that the Dansk/JPGroup heat exchangers have perfectly flat manifold tops to begin with and aftermarket heads may not have been machined well enough.
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